As you've discovered already, your Vivaldi Social account and the blog's account on Vivaldi Social are separate. There's no way to control the blog via Vivaldi Social, i.e. all posts you publish on your vivaldi.net blog get shared to Vivaldi Social and there's no way to edit them further.
The handle of the main account is @[email protected]
The blog's handle is @[email protected]
If your main account is on Mastodon Social, I'd recommend following the blog account on Vivaldi Social and promoting it, for example, by adding a link to your account's bio. Also, boost the posts whenever you publish a new blog post and respond to the blog's comments from your main account.