@D35J Hi, to actually answer your question instead of just giving an opinion on Avast itself:
It's really up to you. If you feel you need the extra features of the extension, like the site reputation rankings, then by all means use it. Just be aware that extensions sometimes cause issues with web-sites that are not always easy to figure out for the user.
Note that Vivaldi's tracker blocker is for privacy, not security, even if the ad-blocker lists will block requests to some known malicious sites.
If running Avast locally it should also block access and warn when attempting to access a malicious site. And I assume the lists it uses are updated more regularly than the public lists used by Vivaldi.
So my opinion is you don't need the extension itself, unless you need the site reputation ranking feature. But keep Avast running locally for overall system security.